I asked the same question on math.se but got no answer there. Since it pertains to my current research, I decided to ask here:
Let $n\in 2\mathbb{N}$ be an even number. I want to evaluate
$$I_n
:=
\int_0^1\mathrm{d} u_1 \cdots \int_0^1 \mathrm{d} u_n \frac{\delta(1-u_1-\cdots-u_n)}{(u_1+u_2)(u_2+u_3)\cdots(u_{n-1}+u_n)(u_n+u_1)}.
$$
For small $n$, this is computable by simply parameterizing the $\delta$ function, and
$I_2 = 1$, $I_3 = \pi^2/4$, $I_4 = 2\pi^2/3$. The values of $I_5$ and $I_6$ are numerically $18.2642 \approx 3\pi^4/16$ and $51.9325\approx 8\pi^4/15$. I strongly suspect that
$$
I_{2n+2} \stackrel{?}{=} (2\pi)^{2n} \frac{(n!)^2}{(2n+1)!} =
\frac{(2\pi)^{2n}}{\binom{2n+1}{n}(n+1)}
= (2\pi)^{2n}\mathrm{B}(n+1,n+1),
$$
where $\mathrm{B}$ is the Beta function. Dividing by $(2\pi)^{2n}$, this is Sloane's A002457. For $I_6$, this conjecture is equivalent to
$$\int_0^1\mathrm{d}x \Bigl(\mathrm{Li}_2(\frac{x-1}{x})\Bigr)^2 \stackrel{?}{=} \frac{17}{180}\pi^4$$
(with $\mathrm{Li}_2$ the dilogarithm), which seems to be true numerically, but I could neither prove it nor find it in the literature.
As a last remark, it is possible to get rid of the $\delta$ function by using the identity
$$I_n = \int_{(0,\infty)^n}\mathrm{d}u \frac{f(\lvert u\rvert_1)}{(u_1+u_2)\cdots(u_n+u_1)} \Bigm/\int_0^\infty\mathrm{d}t \frac{f(t)}{t}$$
for any $f:(0,\infty)\to\mathbb{R}$ that makes both integrals finite. Using $f(t) = t 1_{[0,1]}(t)$ where $1_{[0,1]}$ is the characteristic function of the interval $[0,1]$, one can write $I_n$ as an integral over an $n$-dimensional simplex.
Best Answer
We can think of $I_{n}$ as being a classical partition function for $n$ beads on a circle which cannot pass through each other, with logarithmic interaction potential between each bead and its next-to-nearest neighbors on either side. For $I_{2n}$ the beads fall into two ``colors" which do not have logarithmic interactions with each other; while for $I_{2n+1}$ the beads do not fall into two independent groups.
We make two changes of variable. First, we can label the coordinates of the $k^{th}$ bead as $y_k$, where $y_1=0$ is fixed (exploiting the translation invariance of the problem) and we define $y_{2n+k} = 1+y_k$ (because of the periodic nature of the circle): $$ u_i = y_{i+1}-y_i\ ,\qquad y_1=0\ ,\qquad y_{2n+i}\equiv 1+y_i \ . $$ Then the integral can be written as a path ordered expression without the delta function constraint as $$ I_{n}= \int_0^1 dy_{n} \int_0^{y_{n}} dy_{n-1}\cdots\int_0^{y_3} dy_2\, \prod_{k=1}^{2n}\frac{1}{y_{k+2}-y_k}\ . $$ The second change of variables to $\{y_2,\ldots,y_n\}\to \{s_2,\ldots,s_n\}$ in order change the integration domain to a unit hypercube: $$ y_{k} =\prod_{j=k}^{n} s_{j}\ , $$ with Jacobian $$ J_n = \prod_{j=3}^{n} s_j^{j-2}\ . $$ With this change of variables, $I_{2n}$ becomes (for $n\ge 2$) $$ I_{2n} = \int_0^1 d^{2n-1}{\bf s}\, \prod_{j=2}^{2n-1} \, \frac{1}{1-s_j s_{j+1}} \frac{1}{1-s_{2n}{\bf S}_{2n+1}}\equiv \int_0^1d^{2n-1}{\bf s}\, {\cal F}_{2n}({\bf s})\ $$ where $d^{2n-1}{\bf s}=ds_2\cdots ds_{2n}$, and the integral sign indicates that each of the $s$ variables is being integrated from zero to one, and we have defined $$ {\bf S}_{k}\equiv 1+(-1)^k\prod_{j=2}^{k-2} s_j\ ,\qquad {\cal F}_{2n}({\bf s}) = \prod_{j=2}^{2n-1} \, \frac{1}{1-s_j s_{j+1}} \frac{1}{1-s_{2n}{\bf S}_{2n+1}}\ , $$ with $$ S_3=0\ ,\qquad {\cal F}_{2}({\bf s}) =1\ . $$ Note that for odd $k$, ${\bf S}_k<1$, while for even $k$, ${\bf S}_k>1$. This object ${\bf S}_k$ has the property for any $k$ $$ {\bf S}_{k+1} -s_{k-1} = 1-s_{k-1} {\bf S}_k\ . $$
The strategy is to consider developing a recursion relation when integrating over $ds_{2n}$ and $ds_{2n-1}$, relating $I_{2n}$ to $I_{2n-2}$. To that end it is useful to define the following functions of $x$, $y$ in the domain $ 0<x<1,\ 0<y<1$: $$ {\cal P}_k(x,y) = \frac{1}{(2k)!} \prod_{i=1}^k \left(\pi^2 (2k-1)^2 + \ln^2\left[\frac{1-x}{x(1-y)}\right]\right)\ ,\qquad {\cal P}_0(x,y)\equiv 1\ , $$ and $$ {\cal G}(\alpha,x,y) = \sum_{n=0}^\infty \left(\frac{\alpha}{\pi}\right)^{2n} {\cal P}_n(x,y) = \frac{1}{2 \sqrt{1-\alpha ^2}}\left[\left(\frac{1-x}{x(1-y)}\right)^{c}+\left(\frac{1-x}{x(1-y) }\right)^{-c}\,\right]\ , $$ $$ c\equiv \frac{\sin ^{-1}(\alpha )}{\pi }\ . $$ We generalize the problem to considering the integral $$ {\cal I}_{2n}(\alpha) = \int_0^1d^{2n-1}{\bf s}\, {\cal F}_{2n}({\bf s})\,{\cal G}(\alpha,s_{2n},{\bf S}_{2n+1})\ . $$ We can perform the $s_{2n}$ and $s_{2n-1}$ integrals in ${\cal I}_{2n}$ using the results (using the properties of ${\bf S_k}$ above)
For $0<s_{2n-1}<1$ and $0<{\bf S}_{2n+1}<1$: $$ \frac{1}{2} \int_0^1 ds_{2n} \frac{1}{(1-s_{2n-1} s_{2n})(1-s_{2n}{\bf S}_{2n+1})}\left[ \left(\frac{1-s_{2n}}{s_{2n}(1-{\bf S}_{2n+1})}\right)^c+ \left(\frac{1-s_{2n}}{s_{2n}(1-{\bf S}_{2n+1})}\right)^{-c}\right] = \frac{\pi \csc (\pi c) \left(\left(\frac{1-s_{2n-1}}{1-{\bf S}_{2n+1}}\right)^{-c}-\left(\frac{1-s_{2n-1}}{1-{\bf S}_{2n+1}}\right)^c\right)}{2(s_{2n-1}-{\bf S}_{2n+1})} =\frac{\pi \csc (\pi c)\left(\left(\frac{1-s_{2n-1}}{s_{2n-1}({\bf S}_{2n}-1)}\right)^{-c}-\left(\frac{1-s_{2n-1}}{s_{2n-1}({\bf S}_{2n}-1)}\right)^c\right)}{2(1-s_{2n-1}{\bf S}_{2n})}\ $$
For $0<s_{2n-2}<1$ and $1<{\bf S}_{2n}$: $$ \frac{1}{2} \int_0^1 ds_{2n-1} \frac{1}{(1-s_{2n-2}s_{2n-1})(1-{\bf S}_{2n}s_{2n-1})} \left[ \left(\frac{1-s_{2n-1}}{s_{2n-1}({\bf S}_{2n}-1)}\right)^c- \left(\frac{1-s_{2n-1}}{s_{2n-1}({\bf S}_{2n}-1)}\right)^{-c}\right] = -\frac{\pi \csc (\pi c) \left(\left(\frac{1-s_{2n-2}}{{\bf S}_{2n}-1}\right)^{-c}+\left(\frac{1-s_{2n-2}}{{\bf S}_{2n}-1}\right)^c-2 \cos (\pi c)\right)}{2 (s_{2n-2}-{\bf S}_{2n})} = -\frac{\pi \csc (\pi c) \left(\left(\frac{1-s_{2n-2}}{1-s_{2n-2}{\bf S}_{2n-1}}\right)^{-c}+\left(\frac{1-s_{2n-2}}{1-s_{2n-2}{\bf S}_{2n-1}}\right)^c-2 \cos (\pi c)\right)}{2 (1-s_{2n-2}{\bf S}_{2n-1})} $$
With these integrals we can perform the integrations over $s_{2n}$ and $s_{2n-1}$ in our generalized integral ${\cal I}_{2n}(\alpha)$, obtaining
$$ {\cal I}_{2n}(\alpha) =\int d^{2n-3}{\bf s} \, {\cal F}_{2n-2}({\bf s})\, \left[\pi^2\csc^2(c\pi)\left({\cal G}(\alpha,s_{2n-2},{\bf S}_{2n-1}) -\frac{ \cos c\pi}{ \sqrt{1-\alpha^2}}\right) \right] \, =\int d^{2n-3}{\bf s}{\cal F}_{2n-2}({\bf s})\, \left[\frac{\pi^2}{\alpha^2}\left({\cal G}(\alpha,s_{2n-2},{\bf S}_{2n-1})-1\right) \right] $$ where to get the second line we just plugged in $\pi c=\sin^{-1}\alpha$. Referring to the definition of ${\cal G}$ in eq.(\ref{gdef}), we can equate powers of $\alpha$ on both sides of the above equation with the result that for every $k\ge 0$, $$ \int_0^1d^{2n-1}{\bf s}\, {\cal F}_{2n}({\bf s})\, {\cal P}_k(s_{2n},{\bf S}_{2n+1}) = \int_0^1d^{2n-3}{\bf s}\, {\cal F}_{2n-2}({\bf s})\, {\cal P}_{k+1}(s_{2n-2},{\bf S}_{2n-1}) $$ which is a pretty result.
The above result allows us to write for the desired $2n$-dimensional integrals as one-dimensional integrals $$ I_{2n}=\int_0^1d^{2n-1}{\bf s}\, {\cal F}_{2n}({\bf s})\, {\cal P}_0(s_{2n},{\bf S}_{2n+1}) =\int_0^1ds_2 {\cal P}_{n-1}(s_{2},0)\ . $$ The above results then imply that $$ \sum_{n=0}^\infty \left(\frac{\alpha}{\pi}\right)^{2n} I_{2n+2} = \int_0^1dx\,\sum_{n=0}^\infty \left(\frac{\alpha}{\pi}\right)^{2n} {\cal P}_n(x,0) = \int_0^1dx\, {\cal G}(\alpha,x,0) =\int_0^1dx\frac{1}{2 \sqrt{1-\alpha ^2}}\left[\left(\frac{1-x}{x}\right)^{c}+\left(\frac{1-x}{x }\right)^{-c}\right] = \frac{\sin^{-1}\alpha}{\alpha\sqrt{1-\alpha^2}} = \sum_{n=0}^\infty (2\alpha)^{2n} B(n+1,n+1)\ . $$ Equating powers of $\alpha$ between the first and last expressions answers the posted question.
This solution was found in collaboration with E. Mereghetti (we're physicists, so the language might look odd).