You almost got everything right, and the only problem you have is a minor error when you define $b_n$. You should have
$$b_n=2^n\,(n+1)!=2^n\,\Gamma(n+2)\text{ for }n=1,2,3,\ldots\,.$$
Thus, for each $n=1,2,3,\ldots$,
$$\begin{align}\frac{a_n}{b_n}&=\frac{\Gamma\left(n+\frac12\right)}{\Gamma\left(\frac12\right)\,\Gamma(n+2)}=\frac{2}{\pi}\,\left(\frac{\Gamma\left(n+\frac12\right)\,\Gamma\left(\frac32\right)}{\Gamma(n+2)}\right)\\&=\frac{2}{\pi}\,\text{B}\left(n+\frac12,\frac32\right)\,,\end{align}$$
where $\Gamma$ and $\text{B}$ are the usual gamma and beta functions, respectively. Hence,
$$\frac{a_n}{b_n}=\frac{2}{\pi}\,\int_0^1\,x^{n-\frac12}\,(1-x)^{\frac12}\,\text{d}x\,,$$
so
$$\begin{align}\sum_{n=1}^\infty\,\frac{a_n}{b_n}&=\frac{2}{\pi}\,\int_0^1\,\frac{x^{\frac12}}{1-x}\,(1-x)^{\frac12}\,\text{d}x
\\&=\frac{2}{\pi}\,\int_0^1\,x^{\frac12}\,(1-x)^{-\frac12}\,\text{d}x\,.\end{align}$$
That is, with $u:=x^{\frac12}$, we obtain
$$\begin{align}\sum_{n=1}^\infty\,\frac{a_n}{b_n}&=\frac{4}{\pi}\,\int_0^1\,\frac{u^2}{\sqrt{1-u^2}}\,\text{d}u\\&=\frac{2}{\pi}\,\left(\text{arcsin}(u)-u\,\sqrt{1-u^2}\right)\Big|_{u=0}^{u=1}\,.\end{align}$$
Ergo,
$$\sum_{n=1}^\infty\,\frac{a_n}{b_n}=1\,,$$
whence
$$1+\frac{1\cdot 3}{6}+\frac{1\cdot 3\cdot 5}{6\cdot 8}+\frac{1\cdot3\cdot 5\cdot 7}{6\cdot 8\cdot 10}+\ldots=4\,\sum_{n=1}^\infty\,\frac{a_n}{b_n}=4\,.$$
In fact, one can show that
$$f(z):=\sum_{n=0}^\infty\,\prod_{k=1}^n\,\left(\frac{k-\frac32}{k}\right)\,z^n=(1-z)^{\frac12}$$
for all $z\in\mathbb{C}$ with $|z|\leq 1$. The requested sum satisfies
$$S=8\,\Biggl(1-\frac12-f(1)\Biggr)=4\,.$$
Best Answer
Rewriting the sum as $$2\sum_{k=0}^\infty\frac{(-1)^k2^k}{(2k+1)!!}\left(\frac12\right)^{2k+1}$$ we see the Maclaurin series of the Dawson integral, with argument $\frac12$: $$=2F\left(\frac12\right)=\sqrt\pi e^{-\frac14}\operatorname{erfi}\left(\frac12\right)$$