In fact, the only constraints for the vector $\bf{n}$ are
$1.$ The vector $\bf{n}$ is a unit vector normal to the surface.
$2.$ It should have proper orientation depending on the orientation of the surrounding curve.
So, I think you may have made a mistake in the problem you solved and hence we may help you if you write it down in your question. :)
Verifying Stokes Theorem For Your Question
Your surface is enclosed by the intersection curve of the plane $x+z=1$ and the cylinder $x^2+y^2=36$ as the following figure shows.
The parametric equation of the intersection curve, the tangent vector, and the vector field are
$$\eqalign{
& {\bf{x}} = 6\cos \theta {\bf{i}} + 6\sin \theta {\bf{j}} + \left( {1 - 6\cos \theta } \right){\bf{k}} \cr
& {{d{\bf{x}}} \over {d\theta }} = - 6\sin \theta {\bf{i}} + 6\cos \theta {\bf{j}} + 6\sin \theta {\bf{k}} \cr
& F({\bf{x}}) = xy{\bf{i}} + 2z{\bf{j}} + 6y{\bf{k}} \cr} $$
and hence the line integral will be
$$\eqalign{
& I = \int\limits_C {F({\bf{x}}) \cdot {{d{\bf{x}}} \over {d\theta }}d\theta } = \int_{\theta = 0}^{2\pi } {\left( { - 6\sin \theta xy + 12\cos \theta z + 36\sin \theta y} \right)d\theta } \cr
& \,\,\, = 6\int_{\theta = 0}^{2\pi } {\left( { - 36{{\sin }^2}\theta \cos \theta + 2\cos \theta \left( {1 - 6\cos \theta } \right) + 36{{\sin }^2}\theta } \right)d\theta } \cr
& \,\,\, = 6\int_{\theta = 0}^{2\pi } {\left( { - 36{{\sin }^2}\theta \cos \theta - 12{{\cos }^2}\theta + 36{{\sin }^2}\theta + 2\cos \theta } \right)d\theta } \cr
& \,\,\, = 6\left[ { - 36\int_{\theta = 0}^{2\pi } {{{\sin }^2}\theta \cos \theta d\theta } - 12\int_{\theta = 0}^{2\pi } {{{\cos }^2}\theta d\theta } + 36\int_{\theta = 0}^{2\pi } {{{\sin }^2}\theta d\theta + 2\int_{\theta = 0}^{2\pi } {\cos \theta d\theta } } } \right] \cr
& \,\,\, = 6\left[ { - 36\left( 0 \right) - 12\left( \pi \right) + 36\left( \pi \right) + 2\left( 0 \right)} \right] \cr
& \,\,\, = 144\pi \cr} $$
Next, compute the area element vector $d\bf{S}$ and $\nabla \times {\bf{F}}$
$$\eqalign{
& {\bf{x}} = x{\bf{i}} + y{\bf{j}} + \left( {1 - x} \right){\bf{k}} \cr
& d{\bf{S}} = \left( {{{\partial {\bf{x}}} \over {\partial x}} \times {{\partial {\bf{x}}} \over {\partial y}}} \right)dxdy = \left| {\matrix{
{\bf{i}} & {\bf{j}} & {\bf{k}} \cr
1 & 0 & { - 1} \cr
0 & 1 & 0 \cr
} } \right|dxdy = \left( {{\bf{i}} + {\bf{k}}} \right)dxdy \cr
& dS = \left\| {d{\bf{S}}} \right\| = \sqrt 2 dxdy \cr
& {\bf{n}} = {1 \over {\sqrt 2 }}\left( {{\bf{i}} + {\bf{k}}} \right) \cr
& \nabla \times {\bf{F}} = \left| {\matrix{
{\bf{i}} & {\bf{j}} & {\bf{k}} \cr
{{\partial _x}} & {{\partial _y}} & {{\partial _z}} \cr
{xy} & {2z} & {6y} \cr
} } \right| = 4{\bf{i}} - x{\bf{k}} \cr} $$
I think you had a mistake in this part $d{\bf{S}}=dS {\bf{n}}$ where $\sqrt2$ cancels. Finally, the surface integral will be
$$\eqalign{
& I = \int\!\!\!\int {\nabla \times {\bf{F}} \cdot d{\bf{S}}} = \int_{x = - 6}^6 {\int_{y = - \sqrt {36 - {x^2}} }^{\sqrt {36 - {x^2}} } {\left( {4 - x} \right)dydx} } \cr
& \,\,\,\, = \int_{x = - 6}^6 {2\left( {4 - x} \right)\sqrt {36 - {x^2}} dx} \cr
& \,\,\,\, = \int_{x = - 6}^6 {8\sqrt {36 - {x^2}} dx} = 8\int_{x = - 6}^6 {\sqrt {36 - {x^2}} dx} \cr
& \,\,\,\, = 8\left( {18\pi } \right) = 144\pi \cr} $$
Best Answer
To state Stokes' theorem, Assume that a normal to the surface has been chosen at each point in a "smooth" way. The boundary must be traversed in a way consistent with the choice of normal. Imagine walking along the surface near the boundary with your arms out so that your body points in the direction of the chosen normal. You should traverse the boundary in such a way that your right arm points "outside" the surface.