First, not all functions from the reals to the reals are "polynomial, triginometric, exponential". These form in fact a very tiny subset of all functions. A function is not a formula. It's just that for every $x \in \mathbb{R}$ there exists a unique value $f(x) \in \mathbb{R}$. The unicity is what makes it a function. The asignment of $f(x)$ to $x$ is completely arbitrary, e.g. I could take the 7-th digit in the decimal (infinite) representation of $x$ for all $x > \sqrt{17}$, the 5-th digit of that representation for all $x < \sqrt{17}$ and $f(\sqrt{17}) = \pi$. And this is even relatively nice, because I can write a program for it, but this need not be the case in general. A truly "random" function would just be an infinite list of values, one for each real, assigned all independently of each other. So there is no hope for Taylor expansions etc. Realise that $\mathbb{R}^\mathbb{R}$ is truly a huge set.
The operations on $\mathbb{R}^\mathbb{R}$ are pointwise, so if we have two such functions $f,g$ then we define $f+g$ as a new function, by telling what its value on an arbitrary $x \in \mathbb{R}$ is: $(f+g)(x) = f(x) + g(x)$, i.e. we just add the values of $f$ and $g$ at $x$. Similarly for a scalar $c \in \mathbb{R}$, we define $(c\cdot f)(x) = cf(x)$ for all $x \in \mathbb{R}$, where the latter is just standard multiplication in $\mathbb{R}$. The $0$ is just the function where all values are equal to $0$.
Both have infinite sets of linearly independent elements (or vectors, as elements of a vector space are called, even though they are not "vectors" in the old fashioned sense, like the functions in $\mathbb{R}^\mathbb{R}$): take the functions $f_p$, defined for a fixed $p \in \mathbb{R}$: $f_p(x) = 1$ if $x = p$, and $f_p(x) = 0$ if $x \neq p$. So all $0$ except for a spike at $p$.
Why are the $f_p$ linearly independent? By definition, we need to consider a finite linear combination of distinct $f_{p_i}$: $c_{p_1} \cdot f_{p_1} + \ldots + c_{p_n} \cdot f_{p_n} = 0$ (equality as functions, which means just that they have the same values for all $x$), and we need to show that then all $c_{p_i}$ are $0 \in \mathbb{R}$. Because the equality holds for all $x$, we can use $x = p_1$ in particular. Then $$(c_{p_1} \cdot f_{p_1} + \ldots + c_{p_n} \cdot f_{p_n})(p_1) = c_{p_1}f_{p_1}(p_1) + \ldots + c_{p_n} f_{p_n}(p_1) = 0$$ As $f_{p_2}(p_1) = 0$, as $p_2 \neq p_1$, and so on, but $f_{p_1}(p_1) = 1$ this comes down to $c_{p_1} = 0$. The same idea works for all other coefficients as well. So the set of $f_p$ is linearly independent.
The same idea works in $\mathbb{R}^\mathbb{N}$, the set of sequences, which look more like normal vectors, but of infinite length. We just see this as the set of functions from $\mathbb{N}$ to $\mathbb{R}$ and the same operations and independent functions apply. So both spaces are infinite-dimensional.
If we see $\mathbb{R}^\mathbb{N}$ as a set of functions (as we should) then the function $T$ is just the restriction of $f$ to $\mathbb{N}$. To see that this is linear, take $f,g \in \mathbb{R}^\mathbb{R}$. Then $T(f+g)$ is defined for all $n$ as $(f+g)(n)$, which is in turn defined as $f(n) + g(n)$, and this equals $T(f)(n) + T(g)(n)$, as $T$ does "nothing", it's just the restriction of a function to a smaller domain. The latter sum is just by definition $(T(f) + T(g))(n)$, and as this holds for all $n$ we have equality of functions (or sequences, because we index by $\mathbb{N}$) and $T(f+g) = T(f) + T(g)$. The same can be done for scalars as well.
A matrix for a linear map $T$ is formed by choosing bases for both spaces and computing the base expansion for every $T(b)$ for all basis elements in the domain (as the columns). But here a base for $\mathbb{R}^\mathbb{R}$ is uncountable, so we cannot write it down as a matrix: these can be at most countably infinite in both dimensions.
Best Answer
For a general vector space $V$ it doesn't make sense to talk about infinite sums. I suppose you could define a norm on $V$, as it's a vector space over $\mathbb R$ or $\mathbb C$, but this doesn't generalize to other fields, such as $\mathbb Z / 2$. When it comes to general vector spaces, you can really only talk about finite sums. You can talk about infinite sums in, say, a Hilbert space, but that's a lot more structure.
The very definition of a basis $B \subseteq V$ is that every element in $V$ is a unique finite linear combination of elements in $V$, even if $B$ is infinite. For example, take $V = \{a \in \mathbb R^\mathbb N : a_n = 0 \text{ for all but finitely many } n\}$. Then letting $e_i(j)$ be 1 for $i = j$ and 0 otherwise, we have that $\{e_0, e_1, e_2, e_3, \dots\}$ is a basis for $V$. Although this is infinite, every element of $V$ is a finite linear combination of these basis elements. However, this set is not a basis for $\mathbb R^\mathbb N$. Indeed, the sequence $(1, 1, 1, 1, \dots)$ is not in the span. However, it is a theorem that all vector spaces have a basis, so there is a way to represent all of these sequences as a unique finite linear combination of other sequences. I can't write this basis down for you, as this theorem uses the axiom of choice (and is, in fact, equivalent to it). So if you accept the axiom of choice, your problem can be remedied by just saying "take some basis" without worrying about what it is. If you don't, then there will be some infinite dimensional spaces which don't admit a basis, so you can't always represent vectors in this way.