The condition asks that any pairs out of your choice of vectors should have angle between them greater than $\pi/2$. This gives us certain geometric restraints on how vectors should be organized.
Let $v_1 \in \Bbb{R}^d \setminus \{0\}$ be our first choice and $H_1 = \{ u \in \Bbb{R}^d : u \cdot v_2 \geq 0 \}$. Then our next choice $v_2$ cannot be drawn from this region. But $H_1$ is a closed half-space, which means that half of the $\Bbb{R}^d$ becomes a forbidden region. And as you keep picking vectors, this forbidden region keep expanding. The problem says that when $d = 2$, if you pick 3 vectors in this way, the forbidden region covers the entire plane $\Bbb{R}^2$ and thus you cannot pick the fourth one.
Here is another explanation which is specific to the 2D case. Assume that you have four vectors. Pick any of them and label it $v_1$, and then label the others by $v_2, v_3, v_4$ as they appear in counter-clockwise order beginning from $v_1$. Then the angles $\angle v_1v_2$, $\angle v_2v_3$, $\angle v_3v_4$ and $\angle v_4v_1$ should sum up to $2\pi$. This means that at least one of them should be $\leq \pi/2$.
Best Answer
Since it is a regular hexagon, the vector from $E$ to $F$ is the same as the vector from $O$ to $A$. So we have $\overrightarrow{EF}= 6a$.