What you need to prove is the following:
$$\forall\,v:=(a,b)\in\Bbb R^2\,\,\,\exists\,x,y\in\Bbb R\,\,\,s.t.\,\, v=x(2,1)+y(4,3)\Longleftrightarrow$$
$$\Longleftrightarrow \text{the linear system}\,\,\left\{\begin{array}{}2x+4y=a\\{}\\\;\;x+3y=b\end{array}\right.$$
has a solution for any $\,a,b\in\Bbb R\,$
Now, the above system always has a solution (and, in fact, a unique one for each choice of $\,a,b\in\Bbb R\,$) since the reduced coefficients matrix's determinant is $\,2\cdot 3-1\cdot 4=2\neq 0\,$ , and voilá.
Suppose the vectors $v_1,\dots,v_k$ are linearly dependent.
Then there exist non-trivial (not all zero) coefficients $a_1,\dots,a_k$ so that
$$
a_1v_1+\dots+a_kv_k=0.
$$
Now express this in the basis $B$:
$$
0
=
[a_1v_1+\dots+a_kv_k]_B
=
a_1[v_1]_B+\dots+a_k[v_k]_B.
$$
Therefore the vectors $[v_1]_B,\dots,[v_k]_B$ are linearly dependent.
If you assume that the vectors $[v_1]_B,\dots,[v_k]_B$ are linearly dependent, you can follow the same steps backwards to show that $v_1,\dots,v_k$ are linearly dependent.
We have shown that one set of vectors is linearly dependent if and only if the other one is.
Therefore one set of vectors is linearly independent if and only if the other one is.
Best Answer
This will mainly be an exercise in notation, but here goes...
Let $V=span \{ v_1, ~v_2 ,\dots, v_{k-1} \}$ and let $W=span \{v_1, v_2, \dots, v_k\}$. Seek to show that $V=W$, so we need to show that $V \subseteq W$ and $W \subseteq V$.
Claim $V \subseteq W$:
Claim $W \subseteq V$:
Edit
Note that this proof is relatively atrocious notation--waay too many characters and subscripts floating around, leading to a very bloated proof. A much more elegant proof can be given using summation notation ($\sum$) or with matrices. However, I am inferring that you are in an introductory linear algebra course, so I went with the "brute force" approach to highlight what is really going on, without getting to lost using fancy notation.