If $S$ is an oriented, smooth surface that is bounded by a simple, closed, smooth boundary curve $C$ with positive orientation, then for some vector field $\vec{F}$:
$$\oint_C \vec{F} \cdot d\vec{r} = \iint_S {\rm curl} \> \vec{F} \cdot d\vec{S}$$
The latter integral can be written equivalently as follows for some vector $\vec{n}$, given that it is normal to the surface $S$ and has the proper orientation:
$$\iint_S {\rm curl} \> \vec{F} \cdot \vec{n} \> dS$$
Ultimately, my question is whether or not this normal vector, $\vec{n}$, must be a unit normal vector or not (or if there are other constraints that must be imposed on it). The reason I ask this is because, while working on a problem involving Stokes' Theorem, I deduced that the appropriate normal vector for some surface was $\hat{i} + \hat{k}$, and so I normalized it, yielding $\frac{1}{\sqrt 2}\hat{i} + \frac{1}{\sqrt 2}\hat{k}$.
My answer ended up being off by a factor of $\frac{1}{\sqrt 2}$ which makes me think that how I have defined $\vec{n}$ for these types of problems is incorrect.
[Edit] For those interested, the problem was to evaluate $\oint_C \vec{F} \cdot d\vec{r}$ for $\vec{F}(x, y, z) = xy\>\hat{i} + 2z\>\hat{j} + 6y\>\hat{k}$ such that $C$ is the counterclockwise-oriented curve of intersection of the plane $x + z = 1$ and the cylinder $x^2 + y^2 = 36$.
Best Answer
In fact, the only constraints for the vector $\bf{n}$ are
$1.$ The vector $\bf{n}$ is a unit vector normal to the surface.
$2.$ It should have proper orientation depending on the orientation of the surrounding curve.
So, I think you may have made a mistake in the problem you solved and hence we may help you if you write it down in your question. :)
Verifying Stokes Theorem For Your Question
Your surface is enclosed by the intersection curve of the plane $x+z=1$ and the cylinder $x^2+y^2=36$ as the following figure shows.
The parametric equation of the intersection curve, the tangent vector, and the vector field are
$$\eqalign{ & {\bf{x}} = 6\cos \theta {\bf{i}} + 6\sin \theta {\bf{j}} + \left( {1 - 6\cos \theta } \right){\bf{k}} \cr & {{d{\bf{x}}} \over {d\theta }} = - 6\sin \theta {\bf{i}} + 6\cos \theta {\bf{j}} + 6\sin \theta {\bf{k}} \cr & F({\bf{x}}) = xy{\bf{i}} + 2z{\bf{j}} + 6y{\bf{k}} \cr} $$
and hence the line integral will be
$$\eqalign{ & I = \int\limits_C {F({\bf{x}}) \cdot {{d{\bf{x}}} \over {d\theta }}d\theta } = \int_{\theta = 0}^{2\pi } {\left( { - 6\sin \theta xy + 12\cos \theta z + 36\sin \theta y} \right)d\theta } \cr & \,\,\, = 6\int_{\theta = 0}^{2\pi } {\left( { - 36{{\sin }^2}\theta \cos \theta + 2\cos \theta \left( {1 - 6\cos \theta } \right) + 36{{\sin }^2}\theta } \right)d\theta } \cr & \,\,\, = 6\int_{\theta = 0}^{2\pi } {\left( { - 36{{\sin }^2}\theta \cos \theta - 12{{\cos }^2}\theta + 36{{\sin }^2}\theta + 2\cos \theta } \right)d\theta } \cr & \,\,\, = 6\left[ { - 36\int_{\theta = 0}^{2\pi } {{{\sin }^2}\theta \cos \theta d\theta } - 12\int_{\theta = 0}^{2\pi } {{{\cos }^2}\theta d\theta } + 36\int_{\theta = 0}^{2\pi } {{{\sin }^2}\theta d\theta + 2\int_{\theta = 0}^{2\pi } {\cos \theta d\theta } } } \right] \cr & \,\,\, = 6\left[ { - 36\left( 0 \right) - 12\left( \pi \right) + 36\left( \pi \right) + 2\left( 0 \right)} \right] \cr & \,\,\, = 144\pi \cr} $$
Next, compute the area element vector $d\bf{S}$ and $\nabla \times {\bf{F}}$
$$\eqalign{ & {\bf{x}} = x{\bf{i}} + y{\bf{j}} + \left( {1 - x} \right){\bf{k}} \cr & d{\bf{S}} = \left( {{{\partial {\bf{x}}} \over {\partial x}} \times {{\partial {\bf{x}}} \over {\partial y}}} \right)dxdy = \left| {\matrix{ {\bf{i}} & {\bf{j}} & {\bf{k}} \cr 1 & 0 & { - 1} \cr 0 & 1 & 0 \cr } } \right|dxdy = \left( {{\bf{i}} + {\bf{k}}} \right)dxdy \cr & dS = \left\| {d{\bf{S}}} \right\| = \sqrt 2 dxdy \cr & {\bf{n}} = {1 \over {\sqrt 2 }}\left( {{\bf{i}} + {\bf{k}}} \right) \cr & \nabla \times {\bf{F}} = \left| {\matrix{ {\bf{i}} & {\bf{j}} & {\bf{k}} \cr {{\partial _x}} & {{\partial _y}} & {{\partial _z}} \cr {xy} & {2z} & {6y} \cr } } \right| = 4{\bf{i}} - x{\bf{k}} \cr} $$
I think you had a mistake in this part $d{\bf{S}}=dS {\bf{n}}$ where $\sqrt2$ cancels. Finally, the surface integral will be
$$\eqalign{ & I = \int\!\!\!\int {\nabla \times {\bf{F}} \cdot d{\bf{S}}} = \int_{x = - 6}^6 {\int_{y = - \sqrt {36 - {x^2}} }^{\sqrt {36 - {x^2}} } {\left( {4 - x} \right)dydx} } \cr & \,\,\,\, = \int_{x = - 6}^6 {2\left( {4 - x} \right)\sqrt {36 - {x^2}} dx} \cr & \,\,\,\, = \int_{x = - 6}^6 {8\sqrt {36 - {x^2}} dx} = 8\int_{x = - 6}^6 {\sqrt {36 - {x^2}} dx} \cr & \,\,\,\, = 8\left( {18\pi } \right) = 144\pi \cr} $$