Denote $AB$ the straight line distance between points $A$ and $B$, $r$ the unknown radius of our circle, and $C$ the circle centre.
We thus have an isosceles triangle $ABC$, whose two sides are of length $r$ and the third side is length $AB$.
Let us draw two tangents to our circle - one at point $A$ and the other at point $B$. The tangent at point $B$ will be perpendicular to side $BC$, while the tangent at $A$ will be perpendicular to side $AC$. Thus the two angles $\angle ABC $ and $\angle BAC$ will be $(\frac{\pi}{2}-a)$
Using trigonometry, we obtain $AB=2r\sin a$ so that
$\large r=\frac{AB}{2\sin a}$
Now the angle $\angle BCA$ of our triangle is $2a$ (in radians), so that our arc length $x$ is
$\large x=2\pi r\frac{2a}{2\pi}=2ra=AB\frac{a}{\sin a}$
To find the angles at which the front and back wheels need to be set, let us assume that the wheels are spaced apart by distance $z$ (which is almost the length of our car). The wheels need to be set at tangents to the circle at the points at which they intersect the circle.
We set the back wheels to angle $a$ relative to line $AB$, assuming they are at point $A$. Now we need to find the angle at which to set the front wheels.
Let point $D$ be where the front wheels are - for simplicity we assume they lie on the arc.
We have another isosceles triangle $ACD$, with same angles $\angle CAD$ and $\angle CDA$.
Using trigonometry, we have
$\angle CAD$ = $\angle CDA = \arccos \frac{z}{2r}=\arccos \frac{z\sin a}{AB}$.
Then the angle $\angle DCA = \pi - 2\arccos \frac{z\sin a}{AB}$
If we draw a line from point $D$ that is parallel to $AC$, called $DE$ (where $E$ is left of $D$), the angle $\angle EDC = \angle DCA$, so that the angle the front wheels make relative to $DE$ is
$\large \frac{\pi}{2}-\angle EDC=2\arccos \frac{z\sin a}{AB}-\frac{\pi}{2}$
However it would be better to find the angle of the front wheel relative to a line parallel to $AB$. To do this, we identify a point $F$ to the left of $D$ so that line $FD$ is parallel to $AB$.
As $FD$ is parallel to $AB$ by construction, $\angle CDF+\angle CDA+\angle BAD=\pi$.
Now we have
$\angle BAD=\angle CAD - \angle CAB = \arccos \frac{z\sin a}{AB}-(\frac{\pi}{2}-a)=\arccos \frac{z\sin a}{AB}-\frac{\pi}{2}+a$
Thus
$\angle CDF = \pi - \angle CAD - \angle BAD= \pi-2\arccos \frac{z\sin a}{AB}+\frac{\pi}{2}-a$
This leads to the angle the front wheel makes to $DF$ (which is parallel to $AB$) being
$\large \frac{\pi}{2}-\angle CDF=a+2\arccos\frac{z\sin a}{AB}-\pi$
This result is quite interesting, because as $z$ tends to zero (the car shrinks),
$2\arccos\frac{z\sin a}{AB}\rightarrow \pi$
So that the angle the front wheels make will approach (in value) the angle the rear wheels make i.e. $a$.
If $z$ is non-zero but small, $2\arccos\frac{z\sin a}{AB}<\pi$, so that the front wheel angle will be slightly less than $a$, which is what our intuition would suggest.
Of course, one can just use the distance formula,
$$d((x_1, y_1), (x_2, y_2)) = (x_2 - x_1)^2 + (y_2 - y_1)^2.$$
Alternatively, we can use this to produce a formula that calculates distance specifically between points on the unit circle:
If we regard the points on the unit circle as vectors ${\bf x}, {\bf y}$, the distance formula is
$$d({\bf x}, {\bf y}) = |{\bf x} - {\bf y}|.$$
Now,
$$\phantom{(\ast)} \qquad |{\bf x} - {\bf y}|^2 = ({\bf x} - {\bf y}) \cdot ({\bf x} - {\bf y}) = {\bf x} \cdot {\bf x} - 2 {\bf x} \cdot {\bf y} + {\bf y} \cdot {\bf y} , \qquad (\ast)$$ and since ${\bf x}, {\bf y}$ are on the unit circle, we have after factoring that
$$|{\bf x} - {\bf y}|^2 = 2 (1 - {\bf x} \cdot {\bf y}),$$
so
$$d({\bf x}, {\bf y}) = \sqrt{2 (1 - {\bf x} \cdot {\bf y})}.$$
(Note, by the way, that $(\ast)$ is just the usual Law of Cosines.)
Best Answer
The question is: What is arc length anyway? One possible definition is: For $\epsilon>0$, consider all point sequences $a=x_0,x_1,\ldots, x_n=b$ such that all $x_i$ are on the circle (or in any other set $S$ with respect to which we want to measure an arc length) and the distance $d(x_i,x_{i+1})$ between $x_i$ and $x_{i+1}$ is $<\epsilon$. Let $d_\epsilon(a,b)$ be the infimum of $d(x_0,x_1)+d(x_1,x_2)+\ldots +d(x_{n-1},x_n)$ over all such sequences. Then the arc length from $a$ to $b$ can be defined as $\lim_{\epsilon\to 0} d_\epsilon(a,b)$.
By the triangle inequality, $$d(x_0,x_1)+d(x_1,x_2)+\ldots +d(x_{n-1},x_n)\ge d(x_0,x_n)=d(a,b)$$ for all considered point sequences. Hence $d_\epsilon(a,b)\ge d(a,b)$ for all $\epsilon$, and hence the same inequality holds for the limit. To show that the arc length is in fact strictly greater, pick any point $c$ on the arc between $a$ and $b$, and note that all point sequences with step width $<\epsilon$ have an intermediate point $x_i$ close to $c$ (that is: with $d(x_i,c)<\epsilon$). Hence in the limit we obtain that the arc length from $a$ to $b$ is $\ge d(a,c)+d(c,b)>d(a,b)$, where the last strict inequality follows from the fact that $c$ is not on the straight line segment $ab$.