I can address the second integral:
$$\int_{0}^{\infty }{dx \: \frac{x-\sin x}{\left( {{\pi }^{2}}+{{x}^{2}} \right){{x}^{3}}}}$$
Hint: We can use Parseval's Theorem
$$\int_{-\infty}^{\infty} dx \: f(x) \bar{g}(x) = \frac{1}{2 \pi} \int_{-\infty}^{\infty} dk \: \hat{f}(k) \bar{\hat{g}}(k) $$
where $f$ and $\hat{f}$ are Fourier transform pairs, and same for $g$ and $\bar{g}$. The FT of $1/(x^2+\pi^2)$ is easy, so we need the FT of the rest of the integrand, which turns out to be possible.
Define
$$\hat{f}(k) = \int_{-\infty}^{\infty} dx \: f(x) e^{i k x} $$
It is straightforward to show using the Residue Theorem that, when $f(x) = (x^2+a^2)^{-1}$, then
$$\hat{f}(k) = \frac{\pi}{a} e^{-a |k|} $$
Thus we need to compute, when $g(x) = (x-\sin{x})/x^3$,
$$\begin{align} \hat{g}(k) &= \int_{-\infty}^{\infty} dx \: \frac{x-\sin{x}}{x^3} e^{i k x} \\ &= \frac{\pi}{2}(k^2-2 |k|+1) \mathrm{rect}(k/2) \\ \end{align}$$
where
$$\mathrm{rect}(k) = \begin{cases} 1 & |k|<\frac{1}{2} \\ 0 & |k|>\frac{1}{2} \end{cases} $$
Then we can write, using the Parseval theorem,
$$\begin{align} \int_{0}^{\infty }{dx \: \frac{x-\sin x}{\left( {{\pi }^{2}}+{{x}^{2}} \right){{x}^{3}}}} &= \frac{1}{8} \int_{-1}^1 dk \: (k^2-2 |k|+1) e^{-\pi |k|} \\ &= \frac{\left(2-2 \pi +\pi ^2\right)}{4 \pi
^3}-\frac{ e^{-\pi }}{2 \pi ^3} \\ \end{align}$$
NOTE
Deriving $\hat{g}(k)$ from scratch is challenging; nevertheless, it is straightforward (albeit, a bit messy) to prove that the expression is correct by performing the inverse transform on $\hat{g}(k)$ to obtain $g(x)$. I did this out and proved it to myself; I can provide the details to those that want to see them.
By De Moivre's formula $\sin(x)=\frac{e^{ix}-e^{-ix}}{2i}$ we have the following Fourier sine series:
$$\frac{\sin(3x)\sin(4x)\sin(5x)\cos(6x)}{\sin^2(x)}\\= -\frac{1}{2} \sin(2x)-\frac{1}{2}\sin(4x)+\sin(8x)+\frac{3}{2}\sin(10x)+\frac{3}{2}\sin(12x)+\sin(14x)+\frac{1}{2}\sin(16 x)$$
and:
$$I(n)=\int_{0}^{+\infty}\frac{\sin(2nx)}{x\cosh(x)}\,dx = 2\arctan\left(\tanh\frac{\pi n}{2}\right) $$
follows by differentiation under the integral sign. The original integral can so be expressed in terms of the Gudermannian function:
$$ I = \frac{1}{2} \big(-\text{gd}(\pi)- \text{gd}(2\pi) +
2 \text{gd}(4\pi) + 3 \text{gd}(5\pi) +
3 \text{gd}(6\pi) + 2 \text{gd}(7\pi) +
\text{gd}(8\pi)\big) \approx 7.11363 $$
Best Answer
For the second one,
$$ \begin{align*} \int_{0}^{\infty} \frac{\sin x}{e^x - 1} \; dx &= \int_{0}^{\infty} \frac{\sin x \, e^{-x}}{1 - e^{-x}} \; dx \\ &= \int_{0}^{\infty} \left( \sum_{n=1}^{\infty} \sin x \, e^{-nx} \right) \; dx \\ &\stackrel{\ast}{=} \sum_{n=1}^{\infty} \int_{0}^{\infty} \sin x \, e^{-nx} \; dx \\ &= \sum_{n=1}^{\infty} \frac{1}{1+n^2}, \end{align*}$$
where the starred identity is justified by the following formula
$$ \begin{align*} \int_{0}^{\infty} \frac{\sin x}{e^x - 1} \; dx &= \int_{0}^{\infty} \left( \frac{1 - e^{-Nx}}{1 - e^{-x}} e^{-x} + \frac{e^{-Nx}}{e^x - 1} \right) \sin x \; dx \\ &= \sum_{n=1}^{N} \int_{0}^{\infty} \sin x \, e^{-nx} \; dx + \int_{0}^{\infty} \frac{\sin x \, e^{-Nx}}{e^x - 1} \; dx, \end{align*}$$
together with the dominated convergence theorem. Now the resulting infinite summation can be evaluated in numerous ways. For example, exploiting identities involving the digamma function,
$$ \sum_{n=1}^{\infty} \frac{1}{1+n^2} = \frac{1}{2i} \sum_{n=1}^{\infty} \left( \frac{1}{n-i} - \frac{1}{n+i} \right) = \frac{\psi_0(1+i) - \psi_0(1-i)}{2i} = -\frac{1}{2} + \frac{\pi}{2} \coth \pi. $$
Similar techniques apply to the first integral.