If I read your diagram correctly, the plane defined by vectors $v_1$ and $v_2$ intersects the $x$-$y$ plane at a vector that I'll call $v_3$, the magnitude of which is irrelevant. You want the angle from $v_3$ to $v_2$ and also the angle from $v_3$ to $v_1$. So you can define $v_3 = v_1 + \alpha v_2$ where $\alpha$ is such that the $z$-component of $v_3$ is zero. This value $\alpha$ is well defined given that the $z$-component of $v_2$ is not zero. Once you find $v_3$, you know that you will use the dot product to find the angles.
(At first I thought, if you wanted the angle between the two vectors' projections onto the XY-plane, you could just set each z-component to zero and take the dot product. Of course there is no such angle if either vector has x-component and y-component equal to zero.)
Best Answer
The normal vector to the plane is $n=(3,2,5)$, from that we can find the angles we are interested in using dot product.
For example the angle for the normal with $x-y$ plane, with normal $e_3=(0,0,1)$ is given by
$$\cos \theta=\frac{n\cdot e_3}{|n||e_3|}=\frac{5}{\sqrt{28}}$$