When $K$ is a field not of characteristic $2$, being able to solve $x^2 + y^2 + z^2 = 0$ nontrivially in $K$ is equivalent to being able to solve $x^2 + y^2 = -1$ in $K$, so I will think of the problem from that point of view.
I have checked explicitly that this can be done when $K$ is a quadratic extension of $\mathbf Q_2$ other than $\mathbf Q_2(\sqrt{2})$, as you say you did, and it can also be done when $K = \mathbf Q_2(\sqrt{2})$.
I'll list all seven quadratic extensions of $\mathbf Q_2$ in the order you did:
$$
\mathbf Q_2(\sqrt{-1}), \
\mathbf Q_2(\sqrt{-3}), \
\mathbf Q_2(\sqrt{-5}), \
\mathbf Q_2(\sqrt{-2}), \
\mathbf Q_2(\sqrt{-6}), \
\mathbf Q_2(\sqrt{-10}), \
\mathbf Q_2(\sqrt{2}).
$$
In the four fields $\mathbf Q_2(\sqrt{-1})$,
$\mathbf Q_2(\sqrt{-5})$,
$\mathbf Q_2(\sqrt{-2})$, and
$\mathbf Q_2(\sqrt{-10}),$
it is very easy to see a solution to $x^2 + y^2 = -1$:
$$
0^2 + \sqrt{-1}^2, \
2^2 + \sqrt{-5}^2, \
1^2 + \sqrt{-2}^2, \
3^2 + \sqrt{-10}^2.
$$
In $\mathbf Q_2(\sqrt{-3})$ we have a cube root of unity
$\zeta_3 = (-1 + \sqrt{-3})/2$, for which $1 + \zeta_3 + \zeta_3^2 = 0$, so
$$
-1 = \zeta_3 + \zeta_3^2 = \zeta_3^4 + \zeta_3^2.
$$
In $\mathbf Q_2(\sqrt{-6})$, after playing around a bit I got
$$
\left(\frac{2+\sqrt{-6}}{2}\right)^2 +
\left(\frac{2-\sqrt{-6}}{2}\right)^2 = -1.
$$
That leaves us with $\mathbf Q_2(\sqrt{2})$, whose ring of integers is $\mathbf Z_2[\sqrt{2}]$. I am not going to record here all the numerical work I did (by hand), but just report the final result: we can write
$$
-1 = x^2 + (\sqrt{2} + 2)^2
$$
for some $x \in \mathbf Z_2[\sqrt{2}]$ where $x \equiv 1 \bmod \sqrt{2}^3$. This follows from Hensel's lemma on $\mathbf Q_2(\sqrt{2})$ for the polynomial $f(X) = X^2 + 1 + (\sqrt{2}+2)^2 = X^2 + 7 + 4\sqrt{2}$:
$$
f(1) = 8 + 4\sqrt{2} \Longrightarrow |f(1)|_2 = \frac{1}{4\sqrt{2}}
$$
and
$$
f'(1) = 2 \Longrightarrow |f'(1)|_2^2 = \frac{1}{4}.
$$
Since $|f(1)|_2 < |f'(1)|_2^2$, Hensel's lemma tells us there is a unique solution to $f(x) = 0$ where $x \in \mathbf Z_2[\sqrt{2}]$ and
$|x - 1|_2 < |f'(1)|_2 = 1/2$, or equivalently $x \equiv 1 \bmod (\sqrt{2}^3)$. A more precise form of Hensel's lemma tells us that $|x - 1|_2 = |f(1)/f'(1)|_2 = (1/4\sqrt{2})/(1/2) = 1/2\sqrt{2} = 1/\sqrt{2}^3$, so $x \not\equiv 1 \bmod \sqrt{2}^4$.
We can compute $x$ using the binomial series for the square root:
$$
x = (-7 - 4\sqrt{2})^{1/2} = (1 - 4\sqrt{2} - 8)^{1/2}
$$
so
$$
x = \sum_{n \geq 0} \binom{1/2}{n}(-4\sqrt{2}-8)^n = 1 + \sum_{n \geq 1} \binom{1/2}{n}(-1)^n(4\sqrt{2}+8)^n
$$
Since ${\rm ord}_2\binom{1/2}{n} = -2n + s_2(n)$, where $s_2(n)$ is the sum of the base $2$ digits of $n$, and ${\rm ord}_2((4\sqrt{2}+8)^n) = 5n/2$, the $n$th term of the series
has $2$-adic valuation $5n/2 - 2n + s_2(n) = n/2 + s_2(n)$, so its $\pi$-adic valuation ($\pi = \sqrt{2}$ over the $2$-adics) is twice that: $n + 2s_2(n)$. Since $n+2s_2(n) \geq 7$ for all $n \geq 1$ other than $n = 1$, $2$, and $4$,
$$
x \equiv 1 + \sum_{n = 1, 2, 4} \binom{1/2}{n}(-1)^n(4\sqrt{2}+8)^n \bmod \pi^7\mathbf Z_2[\pi].
$$
Working this out modulo $\pi^7$,
$$
x \equiv 1 + \pi^3 + \pi^5 + \pi^6 \bmod \pi^7\mathbf Z_2[\pi].
$$
In "normal" notation, with $\pi = \sqrt{2}$, this approximate root of $f(X)$ is $9+6\sqrt{2} \bmod 8\sqrt{2}\mathbf Z_2[\sqrt{2}]$. As a check,
$$
(9 + 6\sqrt{2})^2 + (7 + 4\sqrt{2}) = 160 + 112\sqrt{2} = 16\sqrt{2}(5\sqrt{2} + 7),
$$
which is a multiple of $\pi^7 = 8\sqrt{2}$.
In what way did your work suggest that there might not be a solution to $x^2 + y^2 = -1$ in $\mathbf Q_2(\sqrt{2})$?
There is a high-brow explanation for why we found a solution in the particular quadratic extension $\mathbf Q_2(\sqrt{2})$. Being able to solve $x^2 + y^2 = -1$ in a local field $F$ (not of characteristic $2$) is the same as saying the Hilbert symbol $(-1,-1)_F$ is $1$ rather than $-1$. Letting $F = \mathbf Q(\sqrt{2})_v$ be a completion of $\mathbf Q(\sqrt{2})$, Hilbert reciprocity says the number of $v$ such that $(-1,-1)_{\mathbf Q_2(\sqrt{2})_v}$ is $-1$ is even. When $v$ is a place of odd residue field characteristic, $\mathbf Q(\sqrt{2})_v$ is a local field that is an extension of $\mathbf Q_p$ for an odd prime $p$, so that Hilbert symbol is $1$ since we can already solve $x^2 + y^2 = -1$ in $\mathbf Q_p$ (and actually in $\mathbf Z_p$). That leaves us with just three remaining places $v$ on $\mathbf Q(\sqrt{2})$: the two real places (corresponding to the two different embeddings of $\mathbf Q(\sqrt{2})$ into $\mathbf R$) and the unique place over $2$, corresponding to the prime $(\sqrt{2})$ in $\mathbf Z[\sqrt{2}]$.
We obviously can't solve $x^2 + y^2 = -1$ in $\mathbf R$, so
the Hilbert symbol $(-1,-1)_{\mathbf Q(\sqrt{2})_v}$ is $-1$ when $v$ is a real place. That leaves us with just one more place, over $2$, and since the Hilbert symbol is $-1$ at an even number of places it must be $1$ at the place over $2$.
By similar reasoning, if $K$ is an arbitrary real quadratic field, we can describe the non-archimedean places $v$ for which $x^2 + y^2 = -1$ has a solution in $K_v$:
(1) If $v$ lies over an odd prime then there is a solution in $K_v$ since there already is one in $\mathbf Q_p$ for all odd $p$, and $K_v$ contains some $\mathbf Q_p$.
(2) If $v$ lies over $2$ and $2$ does not split completely in $K$, then there is just one $2$-adic place on $K$. We can solve $x^2 + y^2 = -1$ in $K_v$ by Hilbert reciprocity because we can solve it in every other completion except the two real completions, and two is even but three is not.
(3) If $v$ lies over $2$ and $2$ splits completely in $K$ then we can't solve $x^2 + y^2 = -1$ in $K_v$ since $K_v \cong \mathbf Q_2$.
If $K$ is an arbitrary imaginary quadratic field, we can also determine the non-archimedean $v$ for which $x^2 + y^2 = -1$ has a solution in $K_v$:
(1) If $v$ lies over an odd prime then there is a solution in $K_v$ for the same reason as in the real quadratic case above.
(2) If $v$ lies over $2$ and $2$ does not split completely in $K$, then there is exactly one $2$-adic place on $K$. There is also exactly one archimedean place, with completion $\mathbf C$. We can solve $x^2 + y^2 = -1$ in $\mathbf C$, so Hilbert reciprocity implies we can solve $x^2 + y^2 = -1$ in $K_v$. In other words, we can solve $x^2 + y^2 = -1$ in every completion of $K$, so by Hasse-Minkowski we can solve $x^2 + y^2 = -1$ in $K$.
(3) If $v$ lies over $2$ and $2$ splits completely in $K$ then we can't solve $x^2 + y^2 = -1$ in $K_v$ since $K_v \cong \mathbf Q_2$.
The second item of each list for real and imaginary quadratic fields explains why we found solutions in every quadratic extension of $\mathbf Q_2$ other than $\mathbf Q_2(\sqrt{2})$ without needing to work in the completion itself (i.e., a solution in $\mathbf Q(i)$, $\mathbf Q(\sqrt{-3})$, and so on): you wrote every quadratic extension of $\mathbf Q_2$ other than $\mathbf Q_2(\sqrt{2})$ as a $2$-adic completion of an imaginary quadratic field, and in the imaginary quadratic fields that you chose, you can check that $2$ does not split completely (sometimes $2$ ramifies, sometimes $2$ is inert, but $2$ never splits completely). In the case of $\mathbf Q_2(\sqrt{2})$, we can write it as $\mathbf Q_2(\sqrt{-14})$, a completion of $\mathbf Q(\sqrt{-14})$ at its unique $2$-adic place.
Then results above say we have to be to solve $x^2 + y^2 = -1$ in $\mathbf Q(\sqrt{-14})$, and in fact a solution is $x = (2+3\sqrt{-14})/10$ and $y = (6-\sqrt{-14})/10$.
More generally, if $\mathbf Q_2(\sqrt{2}) = \mathbf Q_2(\sqrt{d})$ for some integer $d$ then ${\rm ord}_2(d) = 1$, so $\mathbf Q(\sqrt{d})$ ramifies at $2$ and thus there is a unique $2$-adic place on $\mathbf Q(\sqrt{d})$, so for $d < 0$ we'd be in the same situation as $\mathbf Q(\sqrt{-14})$: there will be a solution to $x^2 + y^2 = -1$ in $\mathbf Q(\sqrt{d})$.
Best Answer
I'll put here what I left as a comment above.
If $k$ is the residue field of $K$ of characteristic $p$, then there is an isomorphism (of groups) $k^{\times} \rightarrow \mu_K^{(p)}$, where $\mu_K^{(p)}$ is the set of roots of unity in $K$ whose order is not divisible by $p$. (This isomorphism is given by the Teichmuller map).
So all that remains is to check the roots of unity of two power order (in fact it suffices to show $i=\sqrt{-1} \not\in K$ which you can do via ramification theory).