Set the center of the circle to be $\left(0,0\right)$. Then the set of points on the circle are those such that $x^2+y^2=r^2$ and the set of points on the line segment are solutions to $y=mx+b$ from some $m$ and $b$ (these are easily found given the two endpoints of the line segment). Substituting, we have
\begin{equation}
x^2+(mx+b)^2=r^2\Longleftrightarrow (m^2+1)x^2+2mbx+(b^2-r^2)=0
\end{equation}
Then this is just a quadratic you can solve with the quadratic formula giving you $x$, and you can get $y$ by $y=mx+b$. However, this gives you two solutions; you must pick the right one (find which is between the two endpoint). Fortunately finding the angle after this is pretty easy: it's just simple trigonometry. If $(x,y)$ is the solution, $\tan^{-1}\left(\frac{y}{x}\right)$ gives you the angles measure counterclockwise from the $x$-axis. You asked for the angle from the $y$-axis, which is then $\frac{\pi}{2}-\tan^{-1}\left(\frac{y}{x}\right).$
A worked example
I'll work out the example you have given. We have radius $r=\frac{3}{2}$, center $\left(3,4\right)$ and a line segment from $(3,3)$ to $(6,7)$. First we'll move the center to $(0,0)$. We do this by subtracting $(3,4)$ from each point. This gives us the center (as desired) of $(0,0)$, and a line segment from $(0,-1)$ to $(3,3)$. Then the line between the two points is $y=\frac{4}{3}x-1$. The equation for the circle is $x^2+y^2=\frac{9}{4}$. Substituting the equation for the line in, we have
\begin{equation}
x^2+\left(\frac{4}{3}x-1\right)^2=\frac{25}{9}x^2-\frac{8}{3}x+1=\frac{9}{4}
\end{equation}
which gives the quadratic
\begin{equation}
\frac{25}{9}x^2-\frac{8}{3}x-\frac{5}{4}=100x^2-96x-45=0
\end{equation}
Then the quadratic equation gives $x=\frac{96\pm \sqrt{96^2+4\cdot 100\cdot 45}}{200}=-0.345,1.305$. We're going to want the solution with positive $x$, so $x=1.305$. Then $y=\frac{4}{3}(1.305)-1=0.740$. To find the desired angles, we merely take $90-\tan^{-1}\left(\frac{0.740}{1.305}\right)=90-29.56=60.44$. I'm not sure what the discrepancy between my answer and the one you provided is; it could be rounding errors, but it is more likely I just made a calculation error somewhere (please do point it out if you see it).
I know it seems like a lot, but the technique is relatively straight forward, the calculation is just some hard work. I hope this answer has shed some light on the process for you.
Using the law of sines you easily get
$$d= \sqrt 2 r \sqrt {1 - \cos x}$$
where d is the hypotenuse of your yellow triangle.
Best Answer
It's just a mathematical problem, first you can find the slope of your lines using (respectively for degrees and radians):
Then, writing down the equations for the intersections of the lines and (half of) the circle, you obtain:
Solving the equation imposing to have a unique solution to have the lines as tangents you obtain the intercept:
and then:
The y of the lower point is just -y1, so the overall distance is, after some simplifications:
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