$\newcommand{\angles}[1]{\left\langle\,{#1}\,\right\rangle}
\newcommand{\braces}[1]{\left\lbrace\,{#1}\,\right\rbrace}
\newcommand{\bracks}[1]{\left\lbrack\,{#1}\,\right\rbrack}
\newcommand{\dd}{\mathrm{d}}
\newcommand{\ds}[1]{\displaystyle{#1}}
\newcommand{\expo}[1]{\,\mathrm{e}^{#1}\,}
\newcommand{\half}{{1 \over 2}}
\newcommand{\ic}{\mathrm{i}}
\newcommand{\iff}{\Longleftrightarrow}
\newcommand{\imp}{\Longrightarrow}
\newcommand{\Li}[1]{\,\mathrm{Li}_{#1}}
\newcommand{\mc}[1]{\mathcal{#1}}
\newcommand{\mrm}[1]{\mathrm{#1}}
\newcommand{\ol}[1]{\overline{#1}}
\newcommand{\pars}[1]{\left(\,{#1}\,\right)}
\newcommand{\partiald}[3][]{\frac{\partial^{#1} #2}{\partial #3^{#1}}}
\newcommand{\root}[2][]{\,\sqrt[#1]{\,{#2}\,}\,}
\newcommand{\totald}[3][]{\frac{\mathrm{d}^{#1} #2}{\mathrm{d} #3^{#1}}}
\newcommand{\ul}[1]{\underline{#1}}
\newcommand{\verts}[1]{\left\vert\,{#1}\,\right\vert}$
$\ds{\int_{0}^{1}{\ln\pars{x}\ln\pars{1 - x} \over 1 + x^{2}}\,\dd x -
\half\int_{0}^{1}{\ln\pars{x}\ln\pars{1 + x^{2}} \over 1 + x^{2}}\,\dd x =
\half\,\ln\pars{2}\,\mrm{G}}$.
$\ds{\mrm{G}:\ \mbox{Catalan Constant.}}$
\begin{align}
&\color{#f00}{\int_{0}^{1}{\ln\pars{x}\ln\pars{1 - x} \over 1 + x^{2}}\,\dd x -
\half\int_{0}^{1}{\ln\pars{x}\ln\pars{1 + x^{2}} \over 1 + x^{2}}\,\dd x}
\\[5mm] = &\
\int_{0}^{1}{\ln\pars{x}\ln\pars{1 - x} \over 1 + x^{2}}\,\dd x -
\Re\int_{0}^{1}{\ln\pars{x}\ln\pars{1 + x\ic} \over 1 + x^{2}}\,\dd x
\label{1}\tag{1}
\end{align}
$\ds{\ln}$-function branch-cut is chosen along the 'negative real axis'. Namely, in $\ds{\left.\vphantom{\large A}\ln\pars{z}\right\vert_{\ z\ \not=\ 0}}$ we have $\ds{-\pi < \mrm{arg}\pars{z} < \pi}$. For instance, when $\ds{x \in \pars{0,1}}$ we have:
\begin{align}
\ln\pars{1 + \ic x} & =
\ln\pars{\root{1 + x^{2}}} + \arctan\pars{x}\ic =
\ol{\bracks{\ln\pars{\root{1 + x^{2}}} - \arctan\pars{x}\ic}}
\\[5mm] & =
\ol{\ln\pars{1 - x\ic}}
\\[5mm] \mbox{and}\ \ln\pars{1 + x^{2}} & =
\ln\pars{1 + x\ic} + \ln\pars{1 - x\ic} = 2\,\Re\ln\pars{1 + x\ic}\quad
\mbox{which we already used in \eqref{1}}.
\end{align}
With the identity
$\ds{ab = \half\,a^{2} + \half\,b^{2} - \half\,\pars{a - b}^{2}}$, the expression \eqref{1} can be rewritten in the form
\begin{align}
&\color{#f00}{\int_{0}^{1}{\ln\pars{x}\ln\pars{1 - x} \over 1 + x^{2}}\,\dd x -
\half\int_{0}^{1}{\ln\pars{x}\ln\pars{1 + x^{2}} \over 1 + x^{2}}\,\dd x}
\\[5mm] = &\
\overbrace{\half\int_{0}^{1}{\ln^{2}\pars{1 - x} \over 1 + x^{2}}\,\dd x}
^{\ds{\color{#f00}{\mc{J}_{1}}}}\
\overbrace{-\,\half\int_{0}^{1}{\ln^{2}\pars{x/\bracks{1 - x}} \over 1 + x^{2}}
\,\dd x}
^{\ds{\color{#f00}{\mc{J}_{2}}}}\
\overbrace{-
\half\,\Re\int_{0}^{1}{\ln^{2}\pars{1 + x\ic} \over 1 + x^{2}}\,\dd x}
^{\ds{\color{#f00}{\mc{J}_{3}}}}
\\[5mm] + &\ \underbrace{%
\half\,\Re\int_{0}^{1}{\ln^{2}\pars{x/\bracks{1 + x\ic}} \over 1 + x^{2}}
\,\dd x}_{\ds{\color{#f00}{\mc{J}_{4}}}}\ =\
\color{#f00}{\mc{J}_{1}} + \color{#f00}{\mc{J}_{2}} +\color{#f00}{\mc{J}_{3}} +\color{#f00}{\mc{J}_{4}}
\end{align}
It turns out that the above integrals can be reduced to the form
$$
\left.\int{\ln^{2}\pars{x} \over a - x}\,\dd x\,\right\vert_{\ a\ \not=\ 0}
\,\,\,\,\,\stackrel{x\ =\ at}{=}\,\,\,\,\,
\int{\ln^{2}\pars{at} \over 1 - t}\,\dd t =
-\int\ln^{2}\pars{at}\,\dd\bracks{\ln\pars{1 - t}}
$$
which can be easily evaluated by successive integration by parts:
\begin{equation}
\int{\ln^{2}\pars{x} \over a - x}\,\dd x =
\left\lbrace\begin{array}{lcl}
\ds{-\ln^{2}\pars{x}\ln\pars{1 - {x \over a}} -
2\ln\pars{x}\Li{2}\pars{x \over a} + 2\Li{3}\pars{x \over a}} & \mbox{if} &
\ds{a \not= 0}
\\
\ds{-\,{1 \over 3}\,\ln^{3}\pars{x}} & \mbox{if} & \ds{a = 0}
\end{array}\right.
\end{equation}
$$
\begin{array}{|c|}\hline\mbox{}\\
\quad\mbox{Hereafter, we'll use this result to evaluate}\
\ds{\braces{\vphantom{\large A}\color{#f00}{\mc{J}_{k}}\,,\ k = 1,2,3,4}}
\quad
\\ \mbox{}\\ \hline
\end{array}
$$
With $\ds{r \equiv 1 + \ic}$:
- $\ds{\large\color{#f00}{\mc{J}_{1}}:\ ?}$.
\begin{align}
\color{#f00}{\mc{J}_{1}} & \equiv
\half\int_{0}^{1}{\ln^{2}\pars{1 - x} \over 1 + x^{2}}\,\dd x\,\,\,\,\,
\stackrel{x\ \mapsto\ \pars{1 - x}}{=}\,\,\,\,\,
\half\int_{0}^{1}{\ln^{2}\pars{x} \over x^{2} - 2x + 2}\,\dd x
\\[5mm] & =
\half\int_{0}^{1}{\ln^{2}\pars{x} \over \pars{x - r}\pars{x - \ol{r}}}\,\dd x =
-\,\half\,\Im\int_{0}^{1}{\ln^{2}\pars{x} \over r - x}\,\dd x =
\color{#f00}{\Im\Li{3}\pars{\half\,r}}\label{J1}\tag{J1}
\end{align}
- $\ds{\large\color{#f00}{\mc{J}_{2}}:\ ?}$.
\begin{align}
\color{#f00}{\mc{J}_{2}} & \equiv
-\,\half\int_{0}^{1}{\ln^{2}\pars{x/\bracks{1 - x}} \over 1 + x^{2}}\,\dd x
\,\,\,\,\,\stackrel{x/\pars{1 - x}\ \mapsto\ x}{=}\,\,\,\,\,
-\,\half\int_{0}^{\infty}{\ln^{2}\pars{x} \over 2x^{2} + 2x + 1}\,\dd x
\\[5mm] & =
-\,\half\int_{0}^{1}{\ln^{2}\pars{x} \over 2x^{2} + 2x + 1}\,\dd x -
\half\int_{0}^{1}{\ln^{2}\pars{x} \over x^{2} + 2x + 2}\,\dd x
\\[5mm] & =
-\,{1 \over 4}\int_{0}^{1}
{\ln^{2}\pars{x} \over \pars{x + r/2}\pars{x + \ol{r}/2}}\,\dd x - \half\int_{0}^{1}{\ln^{2}\pars{x} \over \pars{x + r}\pars{x + \ol{r}}}\,\dd x
\\[5mm] & =
-\,\half\,\Im\int_{0}^{1}{\ln^{2}\pars{x} \over -r/2 - x}\,\dd x -
\half\,\Im\int_{0}^{1}{\ln^{2}\pars{x} \over -r - x}\,\dd x
\end{align}
However,
$$
\left\lbrace\begin{array}{rcl}
\ds{-\,\half\,\Im\int_{0}^{1}{\ln^{2}\pars{x} \over -r/2 - x}\,\dd x} & \ds{=} & \ds{-\,{5 \over 128}\,\pi^{3} - {1 \over 32}\,\ln^{2}\pars{2}\pi -
\Im\Li{3}\pars{-\,{r \over 2}}}
\\[3mm]
\ds{-\,\half\,\Im\int_{0}^{1}{\ln^{2}\pars{x} \over -r - x}\,\dd x} & \ds{=} & \ds{-\Im\Li{3}\pars{-\,{\ol{r} \over 2}}}
\end{array}\right.
$$
Then,
\begin{equation}
\color{#f00}{\mc{J}_{2}} =
\color{#f00}{-\,{5 \over 128}\,\pi^{3} - {1 \over 32}\,\ln^{2}\pars{2}\pi}
\label{J2}\tag{J2}
\end{equation}
- $\ds{\large\color{#f00}{\mc{J}_{3}}:\ ?}$.
\begin{align}
\color{#f00}{\mc{J}_{3}} & \equiv
-\,\half\,\Re\int_{0}^{1}{\ln^{2}\pars{1 + x\ic} \over 1 + x^{2}}\,\dd x
\,\,\,\,\,\stackrel{\pars{1 + x\ic}\ \mapsto\ x}{=}
-\,\half\,\Im\int_{1}^{r}{\ln^{2}\pars{x} \over \pars{2 - x}x}\,\dd x
\\[5mm] & =
-\,{1 \over 4}\,\Im\int_{1}^{r}{\ln^{2}\pars{x} \over 2 - x}\,\dd x -
{1 \over 4}\,\Im\int_{1}^{r}{\ln^{2}\pars{x} \over x}\,\dd x
\end{align}
The remaining integrals are given by:
$$
\left\lbrace\begin{array}{rcl}
\ds{-\,{1 \over 4}\,\Im\int_{1}^{r}{\ln^{2}\pars{x} \over 2 - x}\,\dd x} & \ds{=} &
\ds{{1 \over 96}\,\pi^{3} - {3 \over 32}\,\ln^{2}\pars{2}\pi +
{1 \over 4}\,\ln\pars{2}\,\mrm{G} - \half\,\Im\Li{3}\pars{r \over 2}}
\\[3mm]
\ds{-\,{1 \over 4}\,\Im\int_{1}^{r}{\ln^{2}\pars{x} \over x}\,\dd x}
& \ds{=} &
\ds{{1 \over 768}\,\pi^{3} - {1 \over 64}\,\ln^{2}\pars{2}\,\pi}
\end{array}\right.
$$
Then,
\begin{equation}
\color{#f00}{\mc{J}_{3}} =
\color{#f00}{{3 \over 256}\,\pi^{3} - {7 \over 64}\,\ln^{2}\pars{2}\pi +
{1 \over 4}\,\ln\pars{2}\,\mrm{G} - \half\,\Im\Li{3}\pars{r \over 2}}
\label{J3}\tag{J3}
\end{equation}
- $\ds{\large\color{#f00}{\mc{J}_{4}}:\ ?}$.
\begin{align}
\color{#f00}{\mc{J}_{4}} & \equiv
\half\,\Re\int_{0}^{1}{\ln^{2}\pars{x/\bracks{1 + x\ic}} \over 1 + x^{2}}\,\dd x
\,\,\,\,\,\stackrel{x/\pars{1 + x\ic}\ \mapsto\ x}{=}\,\,\,\,\,
{1 \over 4}\,\Im\int_{0}^{\ol{r}/2}{\ln^{2}\pars{x} \over -\ic/2 - x}\,\dd x
\\[5mm] & =
\color{#f00}{{7 \over 256}\,\pi^{3} + {9 \over 64}\,\ln^{2}\pars{2}\pi +
{1 \over 4}\,\ln\pars{2}\,\mrm{G} - \half\,\Im\Li{3}\pars{r \over 2}}
\label{J4}\tag{J4}
\end{align}
Summarising
$\ds{\pars{~\vphantom{\large A}\mbox{see}\ \eqref{J1}, \eqref{J2}, \eqref{J3}\ \mbox{and}\ \eqref{J4}~}}$:
\begin{equation}
\left\lbrace\begin{array}{rcccccccc}
\ds{\color{#f00}{\mc{J}_{1}}} & \ds{=} &&&&&&&\ds{\Im\Li{3}\pars{r \over 2}}
\\[3mm]
\ds{\color{#f00}{\mc{J}_{2}}} & \ds{=} &
\ds{-\,{5 \over 128}\,\pi^{3}} & \ds{-} & \ds{{1 \over 32}\,\ln^{2}\pars{2}\pi}
&&&&
\\[3mm]
\ds{\color{#f00}{\mc{J}_{3}}} & \ds{=} &
\ds{{3 \over 256}\,\pi^{3}} & \ds{-} & \ds{{7 \over 64}\,\ln^{2}\pars{2}\pi} & \ds{+} &
\ds{{1 \over 4}\,\ln\pars{2}\,\mrm{G}} & \ds{-} &
\ds{\half\,\Im\Li{3}\pars{r \over 2}}
\\[3mm]
\ds{\color{#f00}{\mc{J}_{4}}} & \ds{=} &
\ds{{7 \over 256}\,\pi^{3}} & \ds{+} & \ds{{9 \over 64}\,\ln^{2}\pars{2}\pi} & \ds{+} &
\ds{{1 \over 4}\,\ln\pars{2}\,\mrm{G}} & \ds{-} & \ds{\half\,\Im\Li{3}\pars{r \over 2}}
\end{array}\right.
\end{equation}
The $\ds{\quad\ul{final\ result}\quad}$ is given by:
\begin{align}
&\color{#f00}{\int_{0}^{1}{\ln\pars{x}\ln\pars{1 - x} \over 1 + x^{2}}\,\dd x -
\half\int_{0}^{1}{\ln\pars{x}\ln\pars{1 + x^{2}} \over 1 + x^{2}}\,\dd x}
\\[5mm] = &\
\mc{J}_{1} + \mc{J}_{2} + \mc{J}_{3} + \mc{J}_{4} =
\color{#f00}{\half\,\ln\pars{2}\,\mrm{G}}\,,\qquad
\pars{~\mrm{G}:\ \mbox{Catalan Constant}~}
\end{align}
Complete answer now!$$I=\int_0^\infty \frac{{\arctan(x^2)}}{x^4+x^2+1}dx {\overset{x=\frac1{t}}=}
\int_0^\infty \frac{\arctan\left(\frac{1}{t^2}\right)}{\frac{1}{t^4}+\frac{1}{t^2}+1}\frac{dt}{t^2}\overset{t=x}=\int_0^\infty \frac{{x^2\left(\frac{\pi}{2}-\arctan(x^2)\right)}}{x^4+x^2+1}dx $$
Now if we add the result with the original integral $I$ we get:
$$2I=\frac{\pi}{2}\int_0^\infty \frac{x^2}{x^4+x^2+1}dx+\int_0^\infty \frac{(1-x^2)\arctan(x^2)}{x^4+x^2+1}dx$$
$$\Rightarrow I = \frac12 \cdot \frac{\pi}{2}\cdot \frac{\pi}{2\sqrt 3}-\frac12 \int_0^\infty \frac{(x^2-1)\arctan(x^2)}{x^4+x^2+1}dx=\frac{\pi^2}{8\sqrt 3} -\frac12 J$$
Now in order to calculate $J\,$ we start by performing IBP:
$$J=\int_0^\infty \frac{(x^2-1)\arctan\left(x^2\right)}{x^4+x^2+1}dx =\int_0^\infty \arctan(x^2) \left(\frac12 \ln\left(\frac{x^2-x+1}{x^2+x+1}\right)\right)'dx=$$
$$=\underbrace{\frac{1}{2}\ln\left(\frac{x^2-x+1}{x^2+x+1}\right)\arctan(x^2)\bigg|_0^\infty}_{=0}+\int_0^\infty \frac{x}{1+x^4}\ln\left(\frac{x^2+x+1}{x^2-x+1}\right)dx$$
Substituting $x=\tan\left(t\right)$ and doing some simplifications yields:
$$J=\int_0^\frac{\pi}{2} \frac{2\sin (2t)}{3+\cos(4t)}\ln\left(\frac{2+\sin (2t)}{2-\sin (2t)}\right)dt\overset{2t=x}=\int_0^\pi \frac{\sin x}{3+\cos(2x)}\ln\left(\frac{2+\sin x}{2-\sin x}\right)dx=$$
$$=2\int_0^\frac{\pi}{2}\frac{\sin x}{3+\cos(2x)}\ln\left(\frac{2+\sin x}{2-\sin x}\right)dx=\int_0^\frac{\pi}{2}\frac{\cos x}{1+\sin^2 x}\ln\left(\frac{2+\cos x}{2-\cos x}\right)dx =$$
$$=\frac12\int_0^\pi \frac{\cos x}{1+\sin^2 x}\ln\left(\frac{2+\cos x}{2-\cos x}\right)dx\overset{\large{\tan\left(\frac{x}{2}\right)=t}}=\int_0^\infty \frac{1-t^2}{t^4+6t^2+1}\ln\left(\frac{\color{blue}{t^2+3}}{\color{red}{3t^2+1}}\right)dt$$
Splitting the integral into two parts followed by the substitution $\,\displaystyle{t=\frac{1}{x}}\,$ in the second part gives:
$$\int_0^\infty \frac{1-t^2}{t^4+6t^2+1}\ln(\color{red}{3t^2+1})dt =\int_0^\infty \frac{x^2-1}{x^4+6x^2+1}\ln\left(\color{red}{\frac{x^2+3}{x^2}}\right)dx$$
$$\Rightarrow J=\int_0^\infty \frac{1-x^2}{x^4+6x^2+1} \ln(\color{blue}{x^2+3})dx - \int_0^\infty \frac{1-x^2}{x^4+6x^2+1} {\left(\ln(\color{red}{x^2})-\ln(\color{red}{x^2+3})\right)}dx=$$
$$=2\int_0^\infty \frac{1-x^2}{x^4+6x^2+1}\ln\left(\color{purple}{\frac{x^2+3}{x}}\right)dx=2\int_0^\infty \left(\frac12\arctan\left(\frac{2x}{1+x^2}\right)\right)'\ln\left(\frac{x^2+3}{x}\right)dx=$$
$$=\underbrace{\arctan\left(\frac{2x}{1+x^2}\right)\ln\left(\frac{x^2+3}{x}\right)\bigg|_0^\infty}_{=0}-\int_0^\infty \arctan\left(\frac{2x}{1+x^2}\right)\left(\frac{2x}{x^2+3}-\frac{1}{x}\right)dx$$
$$\Rightarrow J=\int_0^\infty \arctan\left(\frac{2x}{1+x^2}\right)\frac{dx}{x}-\int_0^\infty \arctan\left(\frac{2x}{1+x^2}\right) \frac{2x}{x^2+3}dx=J_1-J_2$$
$$J_1=\int_0^\infty \arctan\left(\frac{2x}{1+x^2}\right)\frac{dx}{x}\overset{\large{x=\tan\left(\frac{t}{2}\right)}}=\int_0^\pi \frac{\arctan( \sin t)}{\sin t} dt\overset{t=x}=2\int_0^\frac{\pi}{2} \frac{\arctan( \sin x)}{\sin x} dx$$
In general, we have the following relation: $$\frac{\arctan x}{x}=\int_0^1 \frac{dy}{1+(xy)^2} \Rightarrow \color{red}{\frac{\arctan(\sin x)}{\sin x}=\int_0^1 \frac{dy}{1+(\sin^2 x )y^2}}$$
$$J_1 = 2\color{blue}{\int_{0}^{\frac{\pi}{2}}} \color{red}{\frac{\arctan\left(\sin x\right)}{\sin x}}\color{blue}{dx}=2\color{blue}{\int_0^\frac{\pi}{2}}\color{red}{\int_0^1 \frac{dy}{1+(\sin^2 x )y^2}}\color{blue}{dx}=2\color{red}{\int_0^1} \color{blue}{\int_0^\frac{\pi}{2}}\color{purple}{\frac{1}{1+(\sin^2 x )y^2}}\color{blue}{dx}\color{red}{dy}$$
$$=2\int_0^1 \frac{\arctan\left(\sqrt{1+y^2}\cdot\tan(x)\right) }{\sqrt{1+y^2}} \bigg|_0^\frac{\pi}{2}=\pi\int_0^1 \frac{dy}{\sqrt{1+y^2}}=\boxed{\pi\ln\left(1+\sqrt 2\right)}$$
In order to evaluate $J_2$ we return the integral before was integrated by parts.
$$J_2=2\int_0^\infty \arctan\left(\frac{2 x} {x^2 +1}\right)\frac{x}{x^2 +3}dx=2\int_0^{\infty}\frac{(x^2-1)\ln(x^2+3)}{x^4+6x^2+1} dx=$$
$$=(\sqrt 2+1)\int_0^{\infty} \frac{\ln(x^2+3)}{x^2+\left(\sqrt 2+1\right)^2} \ dx - (\sqrt 2-1)\int_0^{\infty} \frac{\ln(x^2+3)}{x^2+\left(\sqrt 2-1\right)^2} dx$$
Using the following identity that is valid for $a\ge 0, b>0$:$$\int_0^{\infty} \frac{\ln(x^2+a^2)}{x^2+b^2} \ dx = \frac{\pi}{b}\ln(a+b)$$ $$\Rightarrow J_2=\pi\ln\left(\frac{\sqrt{3}+\sqrt{2}+1}{\sqrt{3}+\sqrt{2}-1}\right)=\boxed{\frac{\pi} {2}\ln(2+\sqrt 3)}$$
So we found that:$$J=\boxed{\pi \ln(1+\sqrt 2) - \frac{\pi} {2} \ln(2+\sqrt 3)}\Rightarrow I= \large\boxed{\frac{\pi^2} {8 \sqrt 3}+\frac{\pi}{4}\ln(2+\sqrt 3)-\frac{\pi}{2} \ln(1+\sqrt 2)}$$
Best Answer
A possible way to calculate it is starting with $x=\frac{\pi }{2}-t$, we then get $$\int _0^{\frac{\pi }{2}}x^2\sec \left(x\right)\ln \left(\sin \left(x\right)\right)\:dx=\frac{\pi ^2}{4}\int _0^{\frac{\pi }{2}}\csc \left(x\right)\ln \left(\cos \left(x\right)\right)\:dx$$ $$-\pi \int _0^{\frac{\pi }{2}}x\csc \left(x\right)\ln \left(\cos \left(x\right)\right)\:dx+\int _0^{\frac{\pi }{2}}x^2\csc \left(x\right)\ln \left(\cos \left(x\right)\right)\:dx.\tag1$$ Notice that the first integral is very simple, as for the second one, it won't be necessary to calculate it if we focus on the third integral.
Employing the well-known expansion for $\ln \left(\cos \left(x\right)\right)$ leads to $$\int _0^{\frac{\pi }{2}}x^2\csc \left(x\right)\ln \left(\cos \left(x\right)\right)\:dx$$ $$=-\ln \left(2\right)\int _0^{\frac{\pi }{2}}x^2\csc \left(x\right)\:dx-\sum _{k=1}^{\infty }\frac{\left(-1\right)^k}{k}\underbrace{\int _0^{\frac{\pi }{2}}x^2\csc \left(x\right)\cos \left(2kx\right)\:dx}_{I_k},\tag2$$ so in order to simplify $I_k$ we'll use the following strategy $$\int _0^{\frac{\pi }{2}}x^2\csc \left(x\right)\cos \left(2kx\right)\:dx=\int _0^{\frac{\pi }{2}}x^2\frac{\cos \left(2kx\right)}{\sin \left(x\right)}\:dx$$ $$I_k=\int _0^{\frac{\pi }{2}}x^2\frac{\cos \left(2kx\right)}{\sin \left(x\right)}\:dx$$ $$I_{n+1}-I_n=\int _0^{\frac{\pi }{2}}x^2\frac{\cos \left(2\left(n+1\right)x\right)-\cos \left(2nx\right)}{\sin \left(x\right)}\:dx=-2\int _0^{\frac{\pi }{2}}x^2\sin \left(\left(2n+1\right)x\right)\:dx$$ $$=-\frac{2\pi \left(2n+1\right)\left(-1\right)^n-4}{\left(2n+1\right)^3}$$ $$I_k-I_0=-\sum _{n=0}^{k-1}\frac{2\pi \left(2n+1\right)\left(-1\right)^n-4}{\left(2n+1\right)^3}$$ $$\int _0^{\frac{\pi }{2}}x^2\csc \left(x\right)\cos \left(2kx\right)\:dx=-2\pi \sum _{n=1}^k\frac{\left(-1\right)^{n+1}}{\left(2n-1\right)^2}+4\sum _{n=1}^k\frac{1}{\left(2n-1\right)^3}+\int _0^{\frac{\pi }{2}}x^2\csc \left(x\right)\:dx.$$ Replacing this in $\left(2\right)$ yields $$=2\pi \sum _{k=1}^{\infty }\frac{\left(-1\right)^k}{k}\sum _{n=1}^k\frac{\left(-1\right)^{n+1}}{\left(2n-1\right)^2}-4\sum _{k=1}^{\infty }\frac{\left(-1\right)^k}{k}\sum _{n=1}^k\frac{1}{\left(2n-1\right)^3}$$ $$=-2\pi \int _0^1\left(\sum _{k=1}^{\infty }\frac{\left(-1\right)^k}{k}\left(1-\left(-x^2\right)^k\right)\right)\frac{\ln \left(x\right)}{1+x^2}\:dx$$ $$-2\int _0^1\left(\sum _{k=1}^{\infty }\frac{\left(-1\right)^k}{k}\left(1-x^{2k}\right)\right)\frac{\ln ^2\left(x\right)}{1-x^2}\:dx$$ $$=-2\pi \int _0^1\frac{\ln \left(x\right)\ln \left(\frac{1-x^2}{2}\right)}{1+x^2}\:dx-2\int _0^1\frac{\ln ^2\left(x\right)\ln \left(\frac{1+x^2}{2}\right)}{1-x^2}\:dx.$$ Lastly, notice that $$-2\int _0^1\frac{\ln \left(x\right)\ln \left(\frac{1-x^2}{2}\right)}{1+x^2}\:dx=\int _0^{\frac{\pi }{2}}x\csc \left(x\right)\ln \left(\cos \left(x\right)\right)\:dx$$ $$\int _0^1\frac{\ln ^2\left(x\right)\ln \left(\frac{1+x^2}{2}\right)}{1-x^2}\:dx=2G^2-\frac{45}{16}\zeta \left(4\right),$$ where in order to obtain such closed-form one can trivially reduce it to the derivatives of the Beta function or exploit symmetry with double integration.
Now that we know what $\left(2\right)$ transformed to, $\left(1\right)$ becomes $$\int _0^{\frac{\pi }{2}}x^2\sec \left(x\right)\ln \left(\sin \left(x\right)\right)\:dx$$ $$=\frac{\pi ^2}{4}\left(-\frac{\pi ^2}{8}\right)-\pi \int _0^{\frac{\pi }{2}}x\csc \left(x\right)\ln \left(\cos \left(x\right)\right)\:dx-2\pi \left(-\frac{1}{2}\int _0^{\frac{\pi }{2}}x\csc \left(x\right)\ln \left(\cos \left(x\right)\right)\:dx\right)$$ $$-2\left(2G^2-\frac{45}{16}\zeta \left(4\right)\right),$$ and finally $$\int _0^{\frac{\pi }{2}}x^2\sec \left(x\right)\ln \left(\sin \left(x\right)\right)\:dx=\frac{45}{16}\zeta \left(4\right)-4G^2.$$